I'm not a huge fan of the Spider-Woman show, but I would like to see it on DVD (along with ALL of Marvel's classic animation shows). Spider-Woman as a character was simply conceived just to protect potential trademarks of female counterparts of famous Marvel characters (to prevent someone like DC making up their own Spider-Woman). To that extent, her comics origin was somewhat convoluted and rushed.
For the show, they virtually made everything up about the whole set-up, with Jessica Drew now working at Justice Magazine with photographer Phil and her nephew Billy at her side. My guess is that the makers were subliminally going for a Spider-Man type set-up with the journalist angle.
The plots of the actual episodes were hopelessly simplistic, but that's to be expected since they were written by the main writer of Super Friends. Spider-Man himself shows up on a couple of occasions, but there's no reference to Peter Parker. With this being his first animated appearance since his 60s show, Spider-Man's voice is quite similar to the 'look at me, I'm a super-hero' style voice he had on the older show. It is nice that the animators finally drew in all his costume's webs this time.
Although Spider-Woman was from the same makers as The New Fantastic Four, DePatie-Freleng clearly learned from their mistakes on their previous Marvel series. Whereas The New Fantastic Four was full of some very badly done animation, Spider-Woman's animation was immeasurably improved in comparison. They still made use of some stock animation, but DePatie-Freleng were clearly on the way to making the far higher standard of animation (thankfully sans most stock animation) that they would produce as Marvel Productions in a couple of years.